Material Safety Data Sheet for Stearyl Amine

Identification

Product Name: Stearyl Amine
Chemical Name: Octadecylamine
Synonyms: N-Octadecylamine, 1-Aminooctadecane
CAS Number: 124-30-1
EC Number: 204-694-6
Recommended Uses: Used in chemical synthesis, textile softening agents, surfactants, anti-static agents, corrosion inhibitors
Manufacturer: Supplier details printed on packaging or accompanying documentation
Emergency Contact: 24-hour emergency response number available with supplier or local chemical emergency network

Hazard Identification

Hazard Class: Corrosive to skin, irritant to respiratory tract
Signal Word: Danger
Pictogram: Corrosion, exclamation mark (GHS classification)
Hazard Statements: Causes severe skin burns and eye damage, may cause respiratory irritation
Precautionary Statements: Avoid breathing dust or vapors, wash thoroughly after handling, wear protective gloves, clothing, and eye/face protection
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Potential Health Effects: Shortness of breath, skin blisters, permanent eye damage if left untreated

Composition / Information on Ingredients

Main Component: Stearyl Amine (Octadecylamine)
Chemical Formula: C18H39N
Concentration: ≥ 98% (by weight)
Impurities: Trace long-chain aliphatic amines, water (<2%)
Other Additives: None typically reported

First Aid Measures

Inhalation: Move affected person to fresh air immediately, keep at rest, seek medical attention if breathing is difficult
Skin Contact: Remove contaminated clothing, rinse affected area under running water for at least 15 minutes, call physician
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if possible, continue rinsing, seek ophthalmological care
Ingestion: Rinse mouth without swallowing, do not induce vomiting, seek immediate medical assistance
Self-Protection: Wear gloves during first aid, avoid exposure to yourself while assisting others

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, sand
Unsuitable Extinguishing Media: Water jet, due to risk of spreading
Hazardous Combustion Products: Nitrogen oxides, carbon monoxide, ammonia, irritating fumes
Special Firefighting Procedures: Full protective gear and self-contained breathing apparatus
Special Hazards: May produce dense, noxious smoke under combustion; containers may rupture if exposed to extreme heat
Firefighting Precautions: Isolate scene, prevent water from contaminating drains or watercourses

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate, use appropriate personal protective equipment
Environmental Precautions: Prevent contamination of soil, waterways, drains
Cleanup Methods: Collect spilled product using non-combustible absorbent material, scoop into secure, labeled containers for disposal
Spillage Response: Wash affected area with soap and water after cleanup; do not return recovered product to the original container

Handling and Storage

Safe Handling: Use in well-ventilated area, avoid contact with skin, eyes, clothing, keep containers tightly sealed when not in use
Storage Conditions: Store at room temperature in dry, cool, well-ventilated area
Incompatible Materials: Avoid contact with acids, oxidizing agents, strong bases
Storage Equipment: Store in corrosion-resistant containers with appropriate inner liners
Hygiene Practices: Avoid eating, drinking, smoking in handling areas; wash hands after use

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limit established for stearyl amine; minimize exposure by engineering controls
Engineering Controls: Use local exhaust ventilation, eyewash stations, safety showers
Personal Protection: Nitrile or neoprene gloves, chemical goggles, faceshield, long-sleeved lab coat
Respiratory Protection: Use approved respirator if ventilation is inadequate
Environmental Controls: Prevent product from reaching sewers or waterways; apply local regulations

Physical and Chemical Properties

Appearance: White solid, flakes, or powder
Odor: Amine-like, fishy
Molecular Weight: 269.52 g/mol
Melting Point: 48 – 52 °C
Boiling Point: Approximately 349 °C at atmospheric pressure
Flash Point: >130 °C (closed cup)
Solubility: Insoluble in cold water, soluble in alcohol, ether, oils
Vapor Pressure: Very low at 20 °C
pH: Strongly basic as an amine
Density: Approx 0.78 g/cm3

Stability and Reactivity

Chemical Stability: Stable under standard conditions of use and storage
Reactivity: May react with acids producing heat and toxic fumes; reacts with strong oxidizing agents
Hazardous Decomposition Products: Ammonia, nitrogen oxides, carbon monoxide
Polymerization: Not known to polymerize under normal conditions
Conditions to Avoid: Excess heat, open flame, incompatible materials

Toxicological Information

Routes of Entry: Inhalation, skin and eye contact, ingestion
Acute Toxicity: Oral LD50 (rat) ~ 300 – 2000 mg/kg; may cause serious injury to mucous membranes
Chronic Effects: Prolonged skin contact may result in dermatitis or sensitization
Corrosive Effects: Severe irritation and burns to skin, eyes, and respiratory tract
Carcinogenicity: Not classified as carcinogenic based on available data
Other Hazards: Reports of respiratory distress or asthma-like symptoms in high-concentration settings

Ecological Information

Aquatic Toxicity: Toxic to aquatic organisms, may cause long-term adverse effects
Persistence and Degradability: Slow biodegradation under typical environmental conditions
Bioaccumulation Potential: Tendency to accumulate in aquatic organisms due to high fat solubility
Mobility in Soil: Limited due to low water solubility; binds to soil particles
Other Effects: Avoid release into natural water systems, as contamination can disrupt aquatic life

Disposal Considerations

Waste Treatment: Dispose of contents and container according to local, regional, and national regulations
Disposal Methods: Incineration preferred where permitted; landfilling approved in engineered facilities only
Packaging Disposal: Empty containers should be triple-rinsed before disposal or recycling
Avoid: Entry into drains, sewers, or waterways; uncontrolled incineration; landfill use without permission

Transport Information

UN Number: 2735
Shipping Name: Amines, liquid, corrosive, n.o.s. (contains Octadecylamine)
Transport Hazard Class: 8 (Corrosive substances)
Packing Group: II or III (check specific concentration and form)
Label: Corrosive
Sea (IMDG): Classified as dangerous goods, require special provisions and documentation
Air (IATA): Air shipments restricted to qualified carriers with special packaging
Road (ADR/RID): Subject to corrosive goods rules; check regional transport requirements

Regulatory Information

Classification: Covered by chemical management regulations in most countries
Labelling: GHS, CLP (EU), OSHA HCS (US) compliant required
Inventory Status: Listed on TSCA (US), EINECS (EU), DSL (Canada), AICS (Australia), ENCS (Japan)
Restrictions: Subject to local occupational health, environmental, and transportation regulations
Worker Protection: Mandatory safety training and provision of personal protective equipment
Reporting Requirements: Covered under various environmental reporting programs, including SARA 313 (US) and REACH (EU)